A CLEAR LAYER THAT TAKES THE HIT.
PPF is a thin, clear sheet of polyurethane with an adhesive on the back. It goes on over your paint, on the panels that take the most punishment.
When a stone, branch or fingernail hits, the film absorbs it instead of your clear coat. If the film gets badly marked, you replace that piece. The paint underneath stays as it was.
A GUARD kit gives you the film already cut to the shape of each panel, with the release liner still on.
8.5 MIL ISN'T 8.5 MM.
Film thickness is measured in mil: thousandths of an inch. Not millimetres. One mil is 0.0254 mm, or 25.4 microns (µm).
So when you see 7.5 or 8.5 mil, that's about 0.2 mm. Roughly two sheets of printer paper. You'll see the edge of the film if you look for it, but it won't change the look of your vehicle.
THE STUFF IT'S MADE OF MATTERS.
Modern PPF is made from TPU (thermoplastic polyurethane): a tough, clear plastic that stretches and springs back. Older and cheaper films often use PVC, which is stiffer and doesn't age as well. These are the properties to look for.
PUT ON WET. HELD ON DRY.
The back of the film has a pressure-sensitive adhesive. Applied dry, it would grab the moment it touched the paint, with no second chances.
So it goes on wet. A slip solution (mostly water) lets the piece float, so you can slide it into position. Then you squeegee the water out, and the adhesive bonds to the clear coat as the last of the moisture dries.